 |
| Dr. Alfredo Luis Morales Ruiz |
Dr. ALFREDO LUIS MORALES RUIZ
·
Date of
Birth: February 8, 1947
·
C. I. N°
2.921.612
·
Married,
4 children, 3 daughters 1 son
·
Av. La
Costa, CR Marina Mar, Edif. El Faro, PB-1, Lecherias,Estado Anzuategui,
Telefono: casa: 414.5098 y
0414.3815481
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1.-
Education:
Degree in Chemistry from the Universidad Central de Venezuela (UCV)
1972, Third Cycle Doctorate in Chemistry from the Université de Poitiers,
France, 1976
Doctorate in Physical Science from the Université de Poitiers, 1978.
2.-
Experience and Achievements: 32 years
of experience. 26 years in the Petroleum Industry.
·
President of MLF
Consultores, C.A., from May 2007
·
Retired of Petroleum of Venezuela, Dic. 2006.
·
President of Petroregional
del Lago, Associate company between
PDVSA and Shell, March 2006- Nov. 2006
·
President of PDVSA
Intevep, Reserch Center of Petroleos of
Venezuela, S.A., Oct. 2004 - March 2006.
·
President of
Petrozuata. Associate Company between
PDVSA and Conoco-Phillips – Jul. 2003
to Oct. 2004.
·
Functional Manager - PDVSA
Strategic Planning - March 2002 / Sept. 2003.
·
Director - CONICIT MC&T
Board of Directors - Jan. 2001 / Mar.
2002
·
Manager - Department of
Emerging Technologies, PDVSA Intevep - 2001 / 2002
·
Vicepresident - National
Foundation for the Advancement of Science - FUNDAVAC - 1997 / 1999
·
Manager - Technical Information Center - PDVSA
Intevep, & Technical Editor of the Magazines "Technological Vision and
the Venezuelan Catalysis Society - 1997 / 2001
·
Manager - Department of
Protection of Technology - PDVSA Intevep - 1995 / 1997
·
Manager - Environmental
Planning and Interpretation - PDVSA Intevep - 1992 / 1995
·
Guest Investigative
Professor at the California Institute of Technology (CALTEC) - Los Angeles -
1990 / 1992
·
Manager - Natural Gas
Industrialization Program - PDVSA - 1987 / 1990
·
Investigator - I&D
Projects in the area of hydrotreatment of heavy crudes, Preparation and Scaling
of Catalizers at the commercial level, development of technologies - 1978 /
1987
·
Appointed Professor to the
Science Faculty, School of Chemistry, Universidead Central de Venezuela - 1978
/ 1983
·
Grant holder of the
National Science and Technology Council (CONICIT) for Master and Doctorate in
France - 1973 / 1978
·
Chemistry Department Chief
in the Venezuelan Institute of Technological and Industrial Investigations
(INVESTI) - 1970 / 1973
3.- National and International
Consultant:
·
From 1997 has been
consultant to the Faculty of Judicial and Political Sciences in the Universidad
de los Andes, Intellectual Property, as thesis judge.
·
From 1997 to 2001, has been
permanent advisor to the Universidad del Zulia Council, assigned to the
Administrative Vicerectorade of said University The activities were focused on
finding and retaining of inventions developed by the University and the
transfer of technology through the country.
·
From 1979 to 1984 worked as
advisor to CONICIT as a member of the Chemical Science Commission for the
evaluation of national projects.
·
In 1993 worked as advisor
for the Technological Investigations Council of Colombia, to establish a
national plan of investigation in catalysis according to the National Plan of
Science and Technology. Priority areas were defined and established accoridng
to the needs of the country, the goals and challenges, and the respective
technological projects.
4.- Developed and Transferred Technologies:
·
INT-R1â: Catalizer for the
demetalizing and desulfuring of residual and heavy crudes with high capacity
for retention and storage of metals. Manufactured on the commercial level with Akzo
Chemical.
·
INT-R2â: Catalizer for the
demetalizing of CXP with low production of coke. Manufactured at the commercial
level and the formula was marketed.
·
INT-GOV-10â e INT-GOV-20â: Catalizers for the HDS/HDN of heavy vacuum
gasoils and gasoils from craqueo
processes.
·
HHCä:
Catalitic Process to hydrotreat gasoils. Technology in PDVSA portfolio.
·
DISOLâ:
Technology to convert natural gas into high grade diesel. Technology in commercial
demonstration phase in PDVSA.
·
BIOTECHNOLOGY: Development of a process to
produce diesel zero sulfur. Currently in development stage.
·
NEW USES
OF PETROLEUM: Conversion of heavy crude in advanced
carbon materials to extend the life of the base of heavy crude resources.
·
NON
CONVENTIONAL GASIFICATION: SOLAR COMBUSTIBLES:
Development of technology at the commercial level to convert CXP to synthesis
gas and hydrogen using solar thermochemistry.
·
ALTERNATE
ENERGY: COMBUSTIBLE CELLS: Technology to use liquid hydrocarbons in
combustible cells.
5.-Publications and Awards:
·
95 scientific works
published in national and international magazines.
·
16 inventions in the USA
that have originated 74 world patents. Four of the inventions have been
marketed by PDVSA and bought by Exxon for their USA and England refineries.
These catalizers were also used by Lagoven for their HDS1 & 2 units, to
protect the catalizer from conventional hydrosulfurization.
·
Awards to the best work in
Chemical Science of CONICIT (1980), IBM
Science and Technology Award (1984 - 1985) Colombian Petroleum Award (1985) and
Achievement Award, first class (1998).
·
Has been postulate to the
National Science Award of Venezuela and of the Technological Development of the
United Nations, and is a member of the Academy of Science of New York.
·
In March 2001, receives the
award for oustanding performance in the publication of scientific,
technological and informative articles in PDVSA.
·
25 articles of opinion in
the national media since 1990-2000.
·
INVENTION PRODUCTION
1. R.
Galiasso, J. A. Salazar, D. Huskey, A. Morales y L. Aquino
" Process for the conversion of
asphaltenes and resins in the presence of steam, ammonia and hydrogen". United States Patent, Nº 4.469.587; sep. 4, 1984
2. A.
Morales, R. Galiasso, M.M. Ramírez de Agudelo, J.A. Salazar
"Catalyst having high metal retention
capacity and good stability for the use
in the demetallization of heavy crudes and method of preparation of same".
United
States Patent, N° 4.520.128, May 28, 1985.
3. A. Morales, R. Galiasso, A.R. Carrasquel
"Process for catalyst preparation for
the hydrodemetallization of heavy crudes and residues". United States Patent, N° 4.525.472, Jun
25, 1985.
4. G. Sepulveda, M. Rosa-Brussin, N. Carrión,
P. Roa, A. Morales. J. Guitian, O. Rodríguez y
C. Zerpa
" Catalyst formed of natural clay for
use in the HDM and hydroconversion of heavy crudes and residues and method of preparation of
same".
United
States Patent N° 4.568.657, Feb, 4,
1986.
5. A. Morales, R. Galiasso, M.M. de Agudelo,
J. A. Salazar, R. Carrasquel
"Process for demetallization of heavy
crudes using a catalyst having high
metal retention capacity and good
stability.
United
States Patent N° 4.579.649, Apr. 1, 1986.
6. A. Morales, R. Galiasso, R. Carrasquel y
J.A. Salazar
"Catalyst for removing sulphur and metal
contaminants from heavy crudes and
residues". United States Patent N°
4.588.709. May 13, 1986.
7. R.
Galiasso, J.A. Salazar, A. Morales and A.R. Carrasquel
"Hydroconversion of heavy crudes with
metal and asphaltenes content in the presence of soluble metallic compounds and water".
United
States Patent N° 4.592.827, jun. 3, 1986.
8. A. Morales, J.A. Salazar, M.M. de Agudelo,
N.P. Martínez, R. Carrasquel
"Catalyst for the hydrocracking of heavy
vacuum gas oils, method of preparation
of catalyst and process for use thereof
in the mild hydrocracking of heavy vacuum gas oils". United
States Patent N° 4.600.703, jul 15, 1986.
9. G.
Sepulveda, M. Rosa-Brussin, N. Carrión, P. Roa, A. Morales, J. Guitián, O.
Rodríguez, C. Zerpa
"Process for the demetallization and
hydroconversion of heavy crudes oils and residues using a natural clay catalyst".
United
States Patent N° 4.613.427, sep. 23, 1986.
10. A. Morales, R. Galiasso, A. R. Carrasquel
y J.A. Salazar
"Catalyst for removing
sulfur and metal contaminant from heavy crude and residues, process using the
catalyst".
United
States Patent N° 4.642.179, Feb. 10, 1987.
11. A. Morales y J.J. García
"Catalyst for hydrotreatment of
distillates of petroleum and method for preparation of same". United
States Patent N° 4.743.574, May 10, 1988.
12. R. Galiasso, A. Morales y J. Salazar
"Hydrocraking High Residual Contained in Vacuum Gas
Oil", United States Patent N° 5.009,768, April 23, 1991
13. C. Ovalles, R. Bolívar, A. Hamana y A.
Morales
"Process for Treating Heavy Crude
Oil", United States Patent N° 5,269,909, Dic,
14, 1993
14.-
Cesar Ovalles, Alfredo Morales, Luis a. Rivas, Nora Urbano,
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Microwave heated catalyst
and process, US Patent N° 6.017.845, Enero 25, 2000.
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15.- Domingo
Rodriguez, Alfredo Morales, Julian Blanco, Manuel Romero, Aldo
Steinfeld, Process for converting heavy
crude oils and petroleum coke to syngas using external source of radiation,
US Patent N° 7.176.246, Febrero 13, 2007.
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INTERNATIONAL PATENT
(Obtained from US Inventions)
1.- Patent Number 4222731 Issue Date: 12/21/95 Status: Issued
Application Number
P4222731.3 Filing Date: 07/10/92 Country Germany
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
2.- Patent Number 2,062,348 Issue Date: 04/02/96 Status: Issued
Application Number
2,062,348-9 Filing Date: 03/05/92 Country Canada
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
3.- Patent Number 5,269,909 Issue Date: 12/14/93 Status: Issued
Application Number
783,788 Filing Date: 10/24/91 Country Usa
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
4.- Patent Number 2260990 Issue Date: 05/31/95 Status: Issued
Application Number
9205105.1 Filing Date: 03/09/92 Country Great Britain
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
5.- Patent Number 01259546 Issue Date: 03/20/96 Status: Issued
Application Number
To92a000347 Filing Date: 04/17/92 Country Italy
Title Process For Treating
Heavy Crude Oils
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
6.- Patent Number 1967886 Issue Date: 09/18/95 Status: Issued
Application Number
4-67927 Filing Date: 03/26/92 Country Japan
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
7.- Patent Number 2045567 Issue Date: 10/10/95 Status: Issued
Application Number
5011265.04 Filing Date: 03/27/92 Country Russia
Title Process For Treating
Heavy Crude Oils
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
8.- Patent Number 180131 Issue Date: 11/17/95 Status: Issued Caso No.
Application Number
9201079 Filing Date: 03/12/92 Country Mexico
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
9.- Patent Number 2682963 Issue Date: 04/05/96 Status: Issued
Application Number
9203520 Filing Date: 03/24/92 Country France
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
10.- Patent Number 25218 Issue Date: 12/10/96 Status: Issued
Application Number
356756 Filing Date: 03/09/92 Country Colombia
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
11.- Patent Number 52.695 Issue Date: 10/07/94 Status: Issued
Application Number 1455
Filing Date: 10/18/91 Country
Venezuela
Title Process For Treating
Heavy Crude Oils.
Inventor 1: Cesar
Ovalles Inventor 2: Antonia
Hamana
Inventor 3: Rafael
Bolivar Inventor 4: Alfredo
Morales
12.- Patent Number 5,009,768 Issue Date: 04/23/91 Status: Issued
Application Number
452,389 Filing Date: 12/19/89 Country Usa
Title Hydrocracking High
Residual Vacuum Gas Oil.
Inventor 1: Roberto
Galiasso Inventor 2: Alfredo Morales
Inventor 3: Jose A. Salazar
13.- Patent Number 52.697
Issue Date: 10/07/94 Status:
Issued
Application Number 1473
Filing Date: 10/23/91 Country
Venezuela
Title Hydrocracking High
Residual Vacuum Gas Oil.
Inventor 1: Roberto
Galiasso Inventor 2: Alfredo
Morales
Inventor 3: Jose A. Salazar
14.- Patent Number 8405477 Issue Date: 10/24/88 Status: Issued
Application Number
8405477 Filing Date: 04/06/84 Country France
Title Process For The
Conversion Of Asphaltenes And Resins In The Presence Of Steam, Ammonia And Hydrogen.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Donald
Huskey Inventor 4: Alfredo
Morales
Inventor 5: Luis Aquino
15.- Patent Number 1435837 Issue Date: 09/05/87 Status: Issued
Application Number
59-062076 Filing Date: 03/29/84 Country Japan
Title Process For The
Conversion Of Asphaltenes And Resins In The Presence Of Steam, Ammonia And
Hydrogen.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Donald
Huskey Inventor 4: Alfredo
Morales
Inventor 5: Luis Aquino
16.- Patent Number De3432378 Issue Date: 09/29/88 Status: Issued
Application Number
P3432378.3 Filing Date: 09/03/84 Country Germany
Title Process For The
Conversion Of Asphaltenes And Resins In The Presence Of Steam, Ammonia And Hydrogen
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Donald
Huskey Inventor 4: Alfredo
Morales
Inventor 5: Luis Aquino
17.- Patent Number 4,469,587 Issue Date: 09/04/84 Status: Issued
Application Number
528,808 Filing Date: 09/02/83 Country Usa
Title Process For The
Conversion Of Asphaltenes And Resins In The Presence Of Steam, Ammonia And Hydrogen.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Donald
Huskey Inventor 4: Alfredo
Morales
Inventor 5: Luis Aquino
18.- Patent Number Pi8401135 Issue Date: 07/25/89 Status: Issued
Application Number
Pi8401135 Filing Date: 03/13/84 Country Brazil
Title Process For The
Conversion Of Asphaltenes And Resins In The Presence Of Steam, Ammonia And Hydrogen.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Donald
Huskey Inventor 4: Alfredo
Morales
Inventor 5: Luis Aquino
19.- Patent Number 1,208,590 Issue Date: 07/29/86 Status: Issued
Application Number
448,011 Filing Date:
02/22/84 Country Canada
Title Process For The
Conversion Of Asphaltenes And Resins In The Presence Of Steam, Ammonia And Hydrogen.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Donald
Huskey Inventor 4: Alfredo
Morales
Inventor 5: Luis
Aquino
20.- Patent Number 46.921
Issue Date: 08/31/88 Status:
Issued
Application Number 0923
Filing Date: 06/19/83 Country
Venezuela
Title Process For The
Conversion Of Asphaltenes And Resins In The Presence Of Steam, Ammonia And Hydrogen.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Donald
Huskey Inventor 4: Alfredo Morales
Inventor 5: Luis
Aquino
21.- Patent Number 2151499 Issue Date: 10/26/88 Status: Issued
Application Number
8431941 Filing Date: 12/18/84 Country Great Britain
Title Catalyst Having High
Metal Retention Capacity And Good Stability For Use In The
Demetallization Of Heavy Crudes And Method Of Preparation Of Same.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
22.- Patent Number 2156847 Issue Date: 12/14/88 Status: Issued
Application Number
8510359 Filing Date: 04/23/85 Country Great Britain
Title Catalyst Having High
Metal Retention Capacity And Good Stability For Use In The
Demetallization Of Heavy Crudes And Method Of Preparation Of Same.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
23.- Patent Number 3446038 Issue Date: 02/18/93 Status: Issued
Application Number
P3446038.1 Filing Date: 12/18/84 Country Germany
Title Catalyst Having High
Metal Retention Capacity And Good Stability For Use In The
Demetallization Of Heavy Crudes And Method Of Preparation Of Same.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A. Salazar
Inventor 5: Angel
Carrasquel
24.- Patent Number 2191957 Issue Date: 10/26/88 Status: Issued
Application Number
8710349 Filing Date: 05/01/87 Country Great Britain
Title Catalyst Having High
Metal Retention Capacity And Good Stability For Use In The
Demetallization Of Heavy Crudes And Method Of Preparation Of Same.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
25.- Patent Number 4,520,128 Issue Date: 05/28/85 Status: Issued
Application Number
563,197 Filing Date: 12/19/83 Country Usa
Title Catalyst Having High
Metal Retention Capacity And Good Stability For Use In The
Demetallization Of Heavy Crudes And Method Of Preparation Of Same.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
26.- Patent Number
Issue Date: Status:
Abandoned
Application Number
8510358 Filing Date: 04/23/85 Country Great Britain
Title Catalyst Having High
Metal Retention Capacity And Good Stability For Use In The
Demetallization Of Heavy Crudes And Method Of Preparation Of Same.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
27.-Patent Number 8419417
Issue Date: 04/30/93 Status:
Issued
Application Number
8419417 Filing Date: 12/19/84 Country France
Title Catalyst Having High
Metal Retention Capacity And Good Stability For Use In The
Demetallization Of Heavy Crudes And Method Of Preparation Of Same.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
28.- Patent Number 49.890
Issue Date: 12/15/93 Status:
Issued
Application Number 0259
Filing Date: 02/20/87 Country
Venezuela
Title Catalyst Having High
Metal Retention Capacity And Good Stability For Use In The
Demetallization Of Heavy Crudes And Method Of Preparation Of Same.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
29.- Patent Number 1,251,197 Issue Date: 03/14/89 Status: Abandoned
Application Number
491,827 Filing Date: 09/30/85 Country Canada
Title A Catalyst Formed Of
Natural Clay For Use In The Hydrodemetallization And Hydroconversion Of Heavy Crudes
And Residues And Method Of Preparation Of Same.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos
Rosa-Brussin
Inventor 3: Nereida
Carrion Inventor 4: Pedro
Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto
Rodriguez Inventor 8:
Carlos Zerpa
30.- Patent Number 3535322 Issue Date: 02/18/93 Status: Abandoned
Application Number
P3535322.8 Filing Date: 10/03/85 Country Germany
Title A Catalyst Formed Of
Natural Clay For Use In The Hydrodemetallization And Hydroconversion Of Heavy Crudes And Residues And Method Of Preparation Of
Same.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos
Rosa-Brussin
Inventor 3: Nereida Carrion Inventor 4: Pedro Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto
Rodriguez Inventor 8:
Carlos Zerpa
31.- Patent Number 1801860 Issue Date: 11/12/93 Status: Abandoned
Application Number
60-221130 Filing Date: 10/03/85 Country Japan
Title A Catalyst Formed Of
Natural Clay For Use In The Hydrodemetallization And Hydroconversion Of Heavy Crudes And Residues And Method Of Preparation Of
Same.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos
Rosa-Brussin
Inventor 3: Nereida
Carrion Inventor 4: Pedro
Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto Rodriguez Inventor 8: Carlos Zerpa
32.- Patent Number 166777 Issue Date: 02/04/93 Status: Abandoned
Application Number 150 Filing Date: 10/03/85 Country Mexico
Title A Catalyst Formed Of
Natural Clay For Use In The Hydrodemetallization And Hydroconversion Of Heavy Crudes And Residues And Method Of Preparation Of
Same.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos
Rosa-Brussin
Inventor 3: Nereida
Carrion Inventor 4: Pedro
Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto
Rodriguez Inventor 8:
Carlos Zerpa
33.- Patent Number
4,568,657 Issue Date: 02/04/86 Status: Issued
Application Number
657,150 Filing Date:
10/03/84 Country Usa
Title A Catalyst Formed Of
Natural Clay For Use In The Hydrodemetallization And Hydroconversion Of Heavy Crudes And Residues And Method Of Preparation Of
Same.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos Rosa-Brussin
Inventor 3: Nereida
Carrion Inventor 4: Pedro
Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto
Rodriguez Inventor 8:
Carlos Zerpa
34.- Patent Number 8514660 Issue Date: 10/24/88 Status: Abandoned
Application Number
8514660 Filing Date: 10/03/85 Country France
Title A Catalyst Formed Of
Natural Clay For Use In The Hydrodemetallization And Hydroconversion Of Heavy Crudes And Residues And Method Of Preparation Of
Same.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos
Rosa-Brussin
Inventor 3: Nereida
Carrion Inventor 4: Pedro
Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto
Rodriguez Inventor 8:
Carlos Zerpa
35.- Patent Number 50.210
Issue Date: 11/12/93 Status:
Issued
Application Number 0261
Filing Date: 02/20/87 Country
Venezuela
Title A Catalyst Formed Of
Natural Clay For Use In The Hydrodemetallization And Hydroconversion Of Heavy Crudes And Residues And Method Of Preparation Of
Same.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos
Rosa-Brussin
Inventor 3: Nereida
Carrion Inventor 4: Pedro
Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto
Rodriguez Inventor 8:
Carlos Zerpa
36.- Patent Number 4,743,574 Issue Date: 05/10/88 Status: Issued
Application Number
817,367 Filing Date: 01/09/86 Country Usa
Title Catalyst For
Hydrotreatment Of Distillates Of Petroleum And Method For The Preparation Of
Same.
Inventor 1: Alfredo
Morales Inventor 2: Juan J.
Garcia
37.- Patent Number 47.688
Issue Date: 03/01/90 Status: Issued
Application Number 1443
Filing Date: 09/12/85 Country
Venezuela
Title Catalyst For
Hydrotreatment Of Distillates Of Petroleum And Method For The Preparation Of
Same.
Inventor 1: Alfredo
Morales Inventor 2: Juan J.
Garcia
38.- Patent Number
Issue Date: Status:
Abandoned
Application Number
460,345 Filing Date:
01/24/83 Country Usa
Title Catalyst For The
Demetallization And Simultaneous Desulfuration Of Complete Heavy Crudes.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
39.- Patent Number 3322884 Issue Date: 10/06/88 Status: Issued
Application Number
P3322884.1 Filing Date: 06/24/83 Country Germany
Title Catalyst For The
Demetallization And Simultaneous Desulfuration Of Complete Heavy Crudes.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
40.- Patent Number 8307998 Issue Date: 05/03/93 Status: Issued
Application Number
8307998 Filing Date: 05/13/83 Country France
Title Catalyst For The
Demetallization And Simultaneous Desulfuration Of Complete Heavy Crudes.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
41.- Patent Number 1221353 Issue Date: 05/05/87 Status: Issued
Application Number
427751 Filing Date: 05/09/83 Country Canada
Title Catalyst For The
Demetallization And Simultaneous Desulfuration Of Complete Heavy Crudes.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
42.- Patent Number Pi8304216 Issue Date: 11/27/90 Status: Issued
Application Number
Pi8304216 Filing Date: 08/05/83 Country Brazil
Title Catalyst For The
Demetallization And Simultaneous Desulfuration Of Complete Heavy Crudes.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
43.- Patent Number 46.931 Issue Date: 08/31/88 Status: Issued
Application Number 1994
Filing Date: 11/16/82 Country
Venezuela
Title Catalyst For The
Demetallization And Simultaneous Desulfuration Of Complete Heavy Crudes.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
44.- Patent Number 4,613,427 Issue Date: 09/23/86 Status: Issued
Application Number
770,098 Filing Date: 08/28/85 Country Usa
Title Process For The
Demetallization And Hydroconversion Of Heavy Crudes And Residues Using A
Natural Clay Catalyst.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos
Rosa-Brussin
Inventor 3: Nereida
Carrion Inventor 4: Pedro
Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto
Rodriguez Inventor 8: Carlos Zerpa
45.- Patent Number 50.482 Issue Date: 11/12/93 Status: Issued
Application Number 1513
Filing Date: 09/23/87 Country
Venezuela
Title Process For The
Demetallization And Hydroconversion Of Heavy Crudes And Residues Using A
Natural Clay Catalyst.
Inventor 1: Gonzalo
Sepulveda Inventor 2: Marcos
Rosa-Brussin
Inventor 3: Nereida
Carrion Inventor 4: Pedro
Roa
Inventor 5: Alfredo
Morales Inventor 6: Jose
Guitian
Inventor 7: Otto
Rodriguez Inventor 8:
Carlos Zerpa
46.- Patent Number 4,642,179
Issue Date: 02/10/87 Status:
Issued
Application Number
834,587 Filing Date: 02/28/86 Country Usa
Title Catalyst For Removing
Sulfur And Metal Contaminants From Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
47.- Patent Number 53.145
Issue Date: 01/09/95 Status:
Issued
Application Number 1630
Filing Date: 10/27/89 Country
Venezuela
Title Catalyst For Removing
Sulfur And Metal Contaminants From Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
48.- Patent Number 4,588,709 Issue Date: 05/13/86 Status: Issued
Application Number
724,969 Filing Date: 04/19/85 Country Usa
Title Catalyst For Removing
Sulfur And Metal Contaminants From Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
49.- Patent Number
Issue Date: Status:
Abandoned
Application Number
85.01693 Filing Date: 06/12/85 Country Holland
Title Catalyst For Removing
Sulfur And Metal Contaminants From Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
50.- Patent Number
Issue Date: Status:
Abandoned
Application Number
60-203222 Filing Date: 09/13/85 Country Japan
Title Catalyst For Removing
Sulfur And Metal Contaminants From Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel Carrasquel Inventor 4: Jose A. Salazar
51.- Patent Number 51.350 Issue Date: 03/18/94 Status: Issued
Application Number 1865
Filing Date: 11/24/88
Country Venezuela
Title Catalyst For Removing
Sulfur And Metal Contaminants From Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel Inventor 4: Jose A.
Salazar
52.- Patent Number 4,600,703 Issue Date: 07/15/86 Status: Issued
Application Number
752,661 Filing Date:
07/08/85 Country Usa
Title Catalyst For The
Hydrocracking Of Heavy Vacuum Gas Oils, Method Of Preparation Of
Catalyst And Process
For Use Thereof In The Mild Hydro-Cracking Of Heavy Vacuum Gas Oils.
Inventor 1: Alfredo
Morales Inventor 2: Jose
A. Salazar
Inventor 3: Magdalena De
Agudelo Inventor 4: Nelson
Martinez
Inventor 5: Angel
Carrasquel
53.- Patent Number 1846782 Issue Date: 06/07/94 Status: Issued
Application Number
61-160668 Filing Date: 07/08/86 Country Japan
Title Catalyst For The
Hydrocracking Of Heavy Vacuum Gas Oils, Method Of Preparation Of
Catalyst And Process
For Use Thereof In The Mild Hydro-Cracking Of Heavy Vacuum Gas Oils.
Inventor 1: Alfredo
Morales Inventor 2: Jose
A. Salazar
Inventor 3: Magdalena De
Agudelo Inventor 4: Nelson
Martinez
Inventor 5: Angel
Carrasquel
54.- Patent Number
Issue Date: Status:
Allowed
Application Number
8601778 Filing Date: 07/08/86 Country Holland
Title Catalyst For The
Hydrocracking Of Heavy Vacuum Gas Oils, Method Of Preparation Of
Catalyst And Process
For Use Thereof In The Mild Hydro-Cracking Of Heavy Vacuum Gas Oils.
Inventor 1: Alfredo
Morales Inventor 2: Jose
A. Salazar
Inventor 3: Magdalena De
Agudelo Inventor 4: Nelson
Martinez
Inventor 5: Angel
Carrasquel
55.- Patent Number 51.932 Issue Date: 07/18/94 Status: Issued
Application Number 0837
Filing Date: 06/08/90 Country
Venezuela
Title Catalyst For The
Hydrocracking Of Heavy Vacuum Gas Oils, Method Of Preparation Of
Catalyst And Process
For Use Thereof In The Mild Hydro-Cracking Of Heavy Vacuum Gas Oils.
Inventor 1: Alfredo
Morales Inventor 2: Jose
A. Salazar
Inventor 3: Magdalena De
Agudelo Inventor 4: Nelson
Martinez
Inventor 5: Angel
Carrasquel
56.- Patent Number 1839668 Issue Date: 04/25/94 Status: Issued
Application Number
61-75385 Filing Date: 04/01/86 Country Japan
Title Process For
Demetallization Of Heavy Crudes Using A Catalyst Having High Metal Retention
Capacity And Good Stability.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
57.- Patent Number
Issue Date: Status:
Abandoned
Application Number
8600756 Filing Date: 03/25/86 Country Holland
Title Process For
Demetallization Of Heavy Crudes Using A Catalyst Having High Metal Retention
Capacity And Good Stability.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
58.- Patent Number 4,579,649 Issue Date: 04/01/86 Status: Issued
Application Number
718,509 Filing Date: 04/01/85 Country Usa
Title Process For
Demetallization Of Heavy Crudes Using A Catalyst Having High Metal Retention
Capacity And Good Stability.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
59.- Patent Number 51.170
Issue Date: 02/16/94 Status:
Issued
Application Number 1601
Filing Date: 10/14/88 Country
Venezuela
Title Process For
Demetallization Of Heavy Crudes Using A Catalyst Having High Metal Retention
Capacity And Good Stability.
Inventor 1: Alfredo
Morales Inventor 2:
Roberto Galiasso
Inventor 3: Magdalena De
Agudelo Inventor 4: Jose A.
Salazar
Inventor 5: Angel
Carrasquel
60.- Patent Number 83 08370 Issue Date: 11/21/88 Status: Issued
Application Number
8308370 Filing Date: 05/20/83 Country France
Title Hydroconversion Of Heavy
Crudes With High Metal And Asphaltene Content In The Presence Of Soluble
Metallic Compouns And Water Vapor.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A. Salazar
Inventor 3: Alfredo
Morales Inventor 4: Angel
Carrasquel
61.- Patent Number Issue
Date: Status: Abandoned
Application Number
461,891 Filing Date:
01/28/83 Country Usa
Title Hydroconversion Of
Heavy Crudes With High Metal And Asphaltene Content In The Presence Of
Soluble Metallic Compouns And Water Vapor.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A. Salazar
Inventor 3: Alfredo
Morales Inventor 4: Angel
Carrasquel
62.- Patent Number 33 20 708 Issue Date: 08/16/90 Status: Issued
Application Number
P3320708.9 Filing Date: 06/08/83 Country Germany
Title Hydroconversion Of
Heavy Crudes With High Metal And Asphaltene Content In The Presence Of
Soluble Metallic Compouns And Water Vapor.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A. Salazar
Inventor 3: Alfredo
Morales Inventor 4: Angel
Carrasquel
63.- Patent Number 1,193,217 Issue Date: 09/10/85 Status: Issued
Application Number
428,034 Filing Date:
05/12/83 Country Canada
Title Hydroconversion Of
Heavy Crudes With High Metal And Asphaltene Content In The Presence Of
Soluble Metallic Compouns And Water Vapor.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A. Salazar
Inventor 3: Alfredo
Morales Inventor 4: Angel
Carrasquel
64.- Patent Number
Issue Date: Status:
Pending
Application Number
Pi8303193 Filing Date: 06/16/83 Country Brazil
Title Hydroconversion Of
Heavy Crudes With High Metal And Asphaltene Content In The Presence Of
Soluble Metallic Compouns And Water Vapor.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A. Salazar
Inventor 3: Alfredo
Morales Inventor 4: Angel
Carrasquel
65.- Patent Number 47.049 Issue Date: 02/16/94 Status: Issued
Application Number 1167
Filing Date: 07/27/88 Country
Venezuela
Title Hydroconversion Of
Heavy Crudes With High Metal And Asphaltene Content In The Presence Of
Soluble Metallic Compouns And Water Vapor.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A. Salazar
Inventor 3: Alfredo
Morales Inventor 4: Angel
Carrasquel
66.- Patent Number 4,592,827 Issue Date: 06/03/86 Status: Issued
Application Number
748,493 Filing Date:
06/25/85 Country Usa
Title Hydroconversion Of
Heavy Crudes With High Metal And Asphaltene Content In The Presence Of
Soluble Metallic Compounds And Water Vapor.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Alfredo
Morales Inventor 4: Angel
Carrasquel
67.- Patent Number
Issue Date: Status:
Abandoned
Application Number
Pi8303478 Filing Date: 06/29/83 Country Brazil
Title Process For Catalyst
Preparation For The Hydrodemetallization Of Heavy Crudes And Residues
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel
68.- Patent Number 4,525,472 Issue Date: 06/25/85 Status: Issued
Application Number
469,079 Filing Date: 02/23/83 Country Usa
Title Process For Catalyst
Preparation For The Hydrodemetallization Of Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel
69.- Patent Number 83 08371 Issue Date: 12/22/89 Status: Abandoned
Application Number
830837178 Filing Date: 05/20/83 Country France
Title Process For Catalyst
Preparation For The Hydrodemetallization Of Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel
70.- Patent Number 167048 Issue Date: 02/26/93 Status: Abandoned
Application Number
197557 Filing Date: 06/07/83 Country Mexico
Title Process For Catalyst
Preparation For The Hydrodemetallization Of Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel
71.- Patent Number 50.200
Issue Date: 11/12/93
Status: Issued
Application Number 0233
Filing Date: 02/16/87 Country
Venezuela
Title Process For Catalyst
Preparation For The Hydrodemetallization Of Heavy Crudes And Residues.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel
72.- Patent Number 43.827
Issue Date: 08/07/86
Status: Issued
Application Number 0019
Filing Date: 01/08/81 Country
Venezuela
Title Metodo Para La
Preparacion De Un Catalizador Para La Desmetaliza-Cion De Crudos Pesados.
Inventor 1: Alfredo Morales
73.- Patent Number 46.668 Issue Date: 08/31/88 Status: Issued
Application Number
1574 Filing Date: 09/09/82 Country Venezuela
Title Hidroconversion De
Crudos Pesados Con Alto Contenido De Metales Y Asfaltenos Mediante Dos Etapas
De Hidrotratamiento.
Inventor 1: Roberto
Galiasso Inventor 2: Jose A.
Salazar
Inventor 3: Alfredo
Morales Inventor 4: Rafael
Blanco
74.- Patent Number 50.202 Issue Date: 11/12/93 Status: Issued
Application Number
0235 Filing Date: 02/16/87 Country Venezuela
Title Metodo Para La
Preparacion De Un Catalizador Para Uso En El Hidro-Tratamiento De Crudos
Pesados Y Residuos.
Inventor 1: Alfredo
Morales Inventor 2: Roberto
Galiasso
Inventor 3: Angel
Carrasquel
SCIENTIFIC
PUBLICATIONS
1. I. Posner, V. Bosch y A. Morales
"Un nuevo método para la determinación
de la Lipoprotenía Lipasa, utilizando
Celite cubierto de
trioleína". Bol. Médico del
Hospital Militar, vol. 2, N° 3, 1971.
2. I.
Posner y A. Morales
"Mechanism of enzyme and substrate activation by Lipoprotein Lipasa
coafactores. I - A specific requirement of physiological concentration
of calcium for enzume activity". J. Biol. Chem., 667, 2265, 1972.
3. P. Hobbes y A. Morales
"Spring of the Espíritu Santo Valley, Margarita Island". Bol. Acad. Ciencias, Fis., Mat. y Nat.,
vol. 99, 95-100, 1973.
4. A, Morales, J. Barbier y R.
Maurel
"Sensibilidad a la estructura del
catalizador de las reacciones de intercambio del benceno y del ciclopentano con
el deuterio", Rev. Química
Portuguesa, N° 18, 158-62, 1976.
5. J.
Barbier, A. Morales y R. Manurel
"Activité des catalyseurs metalliques.
VIII. - Etude de la reaction d'
hydrogenolyse de 1' ethane sur
Pt/A12O3 de dispersions variables".
Bull. Soc. Chim. France, N° 1/2, I31, 1978.
6. J. Barbier, P. Marecot, A.
Morales y R. Maurel
"Activité des catalyseurs metalliques. VIII.- Etude de la
reaction d' hydrogenolyse du cyclopenyane sur Pt/ A1203 de dispersión variables". Bull. Soc. Chim. de France, N°
7-8, -1-1309, 1978.
7. R-Z..C. Van Meerten, A. Morales, J. Barbier y
R. Maurel
"Isotope effects in
the hydrogenation and echange of benzene on platinum and nickel". J. of
Catalysis, 58, 43-51, 1979.
8. A. Morales, P. Marecot, J.
Barbier y R. Maurel
" Efecto del envenamiento sobre la cinética de
la reacción de hydrogenólisis del ciclopentano". Acta Científica Venezolana, 30 (4), 373, 1979.
9. A. Morales, J. Barbier y R. Maurel
"Estudio
comparativo de las reacciones de deuteración e intercambio del benceno sobre
Pt/A12O3". Acta Científica
Venezolana, 30(4), 377, 1979.
10. J. Barbier, A, Morales, P. Merecot y R, Maurel
"Influence of the
dispersion of plantinum and effect of
poisons an its activity and selectivity
for various test reactions". Bull.
Soc. Chim Belges, 88, 78, 1979.
11. J. Barbier, A. Morales y R. Maurel
"Activity of metallic
catalysts.- XI .- Surface structure sensitivity on Pt/A12O3 of cis- 1,2 Dimethil cyclohexane epimerization and
isotopic multiple echange between cyclopentane and deuterium". Nouveau Journal de Chimie, vol.
4, N° 4, 223, 1980.
12. P. Andreú, R. Galiasso, A. Morales, O. Abrams,
L. Katan, L. Pantoja, P. Sojo y E. Vergara
"Adsorption mechanism
of Boscan Porphyrins on hidrodemetallization catalysts. I. - Adsorption on supports".
VII International Congress on Catalysis, Tokyo, Edited by T. Seiyama and K.. K. Tanabe, Part B, 877-886, 1980.
13. A. Morales, J. Barbier y R, Maurel
"Efecto
del tamaño de los critalitos de platino sobre
la reacción de intercambio Etano-Deuterio". Acta
Científica Venezolana, 31, 535-540,
1980.
14. O. Abrams, P. Andréu, A. Ayerbe, R
Galiasso, L . Katan y A. Morales
"Adsorption mechanism
of Boscan porphyrins on hydrodesmetallization catalysts. II.
- Adsorption on oxides and
CoMo/Alumina".
Actas de VII Simposio Iberoamericano de
Catálisis, La Plata, Argentina, vol. I, 344-352, 1980.
15. C. Apesteguía, A. Morales, P. Merecot, J.
Barbier
"Estudio
de la reacción de hydrogenólisis del ciclopetano sobre Pt/A12O3".
Actas del VII Simposio Iberoamericano de
Catálisis, La Plata, Argentina, vol. I, 344-352, 1980.
16. L. Aquino, J. Pachano, J. Guitian, J. Krasuk y
A. Morales
"Desmetallization and
desulphurization of deasphalted oils of heavy Venezuelan crudes". Rev.
Técnica INTEVEP, vol. 1,-1, 3-8, 1981.
17. A. Morales y R. Galiasso
"Adsorption mechanism
of Boscan prophyrins on MoO3, Co3O4 and CoMo/A12O3". Fuel,
61:13-117, 1982.
18. A, Morales, R. Carrasquel y N. P. Martínez
"Acidic extraction of
cobalt and molybdenum from HDS Catalysts". Rev. Técnica INTEVEP, vol.
2-1, 41-47, 1982.
19. L. Aquino, J. Pachano, J. Guitian, J.
Krasuk y A. Morales
"Demetalización
y desulfurización de crudos pesados venezolanos". Petroleo International, N°
1, enero, 30-41, 1982.
20. A. Morales, M. Aguiar y R. Galiasso
"Adsorption mechanism of Boscan porphyrins on HDM oxide
catalysts". Actas del VIII Simposio Iberoamericano de Catálisis, Huelvas,
España, vol. II, 663-670, 1982.
21. O. Abrams, L. Katan, M. La Rosa, A.
Morales, R. Prada y C. Scott
"Estudio
de catalizadores de HDS en reacciones de desmetalización. I. Molibdeno
sobre alúmina". Actas del VIII Simposio Iberoamericano de
Catálisis, Huelva, España, vol. II, 653-662, 1982.
22. R. Galiasso y A. Morales
"Diffusion of vanadium
organo-metallic molecules in hidrodemetallization catalysts" . Rev. Técnica INTEVEP, vol 3
N° 1, 59-68, enero 1983.
23. R. Galiasso y A. Morales
"Mechanism of
adsorption of Boscan Porhyrins on HDM Catalysts
III.- Diffusion of
porphyrins". Appl Catal, vol. 6,
57-74, 1983.
24. A. Morales, R. Galiasso, D. Huskey y
R. Carrasquel
"Catalizador para la hidrodesulfuración y
la hidrodesmetalización de crudos pesados completos", 49th Asistencia Recíproca Pet. Estatal Latinoamericano. Experts Conf. (Mex 1983). Bol.. Tec. Arpel, 12-3,
1983.
25. A. Morales, N.P. Matínez, J. Laine, E.
Payen y J. Grimblot
"Coorelation between
HDS or HDV activity with spectroscopic
characterization of Mo/A12O3 catalysts
modified by extraction". Appl Catal, 6, 329, 1983.
26 A. Morales, M. Aguiar y R. Galiasso
"Mechanism of
adsorption of Boscan Porphyrins on HDM catalysis. IV. Adsorption on Mo/A12O3 oxide catalysts". J. of
Catalysis, en curso.
27. A. Morales, C. Marrero y R. Galiasso
"Adsorption Mechanism of Boscan
Porphyrins on HDM Catalysts. V. Adsorption
on Reduced or sulfided catalysts".,
Proc. of 8th International
Congress on Catalysis, Berlin, vol. II, Pág. 329-340, 1984.
28. A. Morales, J.J. García y R. Prada
"Mechanism and Kinetic
model for HDM reactions, Proc. 8th International
Congress on Catalysis, Berlin, vol
. II, 341-350, 1984.
29. A. Morales, M.M. Ramírez de Agudelo, R.
Carrasquel y Carmen Galarraga
"Hydrotreatment of
heavy gas oils. I.- Evaluation and characterization of catalysts", Proc. IX Simposio Iberoamericano de
Catálisis, Portugal, vol. II, 153, 1984.
30. A. Morales, M.M. Ramírez de Agudelo, J.J.
García y P. Andréu
"Efecto
promotor del cobalto y del níquel eb catalizadores Co(Ni) Mo-A12O3 sobre
la hidrodesulfuración". Trabajo
Invitado, Proc. IX Simposio
Iberoamericano de Catálisis, Portugal, vol.
II, 163, 1984.
31. A. Morales y Adelina de Salazar
"Estrategia
de preparación, comercialización y licenciamiento de catalizadores en
Venezuela", Actas del I Seminario de Refinación de la Industria Petrolera Nacional,
Valencia 1984.
32. H. Kum, J.J. García, A. Morales, L. Caprioli, R. Galiasso y A. de
Salazar
"Hidrotratamiento
de crudos pesados", Actas del I Seminario de Refinación de la
Industria Petrolera Nacional, Valencia,
1984.
33. C. González, J.A. Salazar, E. Rodríguez,
A. Morales y R. Galiasso
"Desarrollo
de un test de desactivación acelerada para mild hydrocracking", Actas del I Seminario de Refinación de la Industria Petrolera
Nacional, Valencia, 1984.
34. H. Kum, J. García, A. Morales, L.
Caprioli, R. Galiasso, y A. de Salazar
"Hidrotratamiento
de crudos pesados y residuales, Actas del LIII Reunión de Expertos de ARPEL, Caracas, 8-11 de octubre. Bol. Técnico ARPEL, 13(4), 239-251,
1984, y Rev. Técnica INTEVEP, 5(1): 17-27, enero 1985.
35. A. de Salazar, M.M. Ramírez de Agudelo y
A. Morales
"Hidrotratamiento
de Gasóleos de vacío pesado. III. Influencia de la acidéz sobre el MHC". Actas del II Coloquio Franco-Venezolano de
Catálisis, IFP Ed., N° A, 1-9, 1985.
36. A. Morales, Armando Salazar y E. Rodríguez
"Hidrotratamiento
de Gasóleos de vacío pesados. IV.- Hidrocraqueo
suave(MHC)".
Actas del II Coloquio Franco-Venezolano
de Catálisis, IFP Ed. Parte Desmetalización, N° B, 1-10, 1985.
37. G. Sepulveda, M. Rosa-Brussin, N. Carrión
y A. Morales
"HDM
e hidroconversión de crudos pesados con catalizador natural". Actas del II Coloquio Franco-Venezolano de Catálisis, IFP
Ed. Parte Desmetalización, N° C, 1-8,
1985.
38. R. Galiasso, A. Salazar, R. Blanco y A.
Morales
"Hydrovisbreaking of
Cerro Negro Crude Oil". Journal of the Japan Petroleum Inst.,
Sekiyu Gakkaishi, vol. 28, N° 1, 54-62, 1985.d
39. A. Morales, A. Salazar y E. Rodríguez
"Hidrocraqueo
suave de gasóleos de vacío pesados para la producción de destilados
medios". Conferencia por invitación, 3o.
Seminario de Catalise, Petrobras, Brasil, IBP Editores, vol. 1,
037-048, 21-23 de agosto 1985.
40. A. Morales y M-M. Ramírez de Agudelo
"Promoter role of Co
(and Ni) in modified Co(Ni)Mo-A12O3 catalysts for hidrodesulfurization
reactions". Appl
Catal, 23, 23-34, 1986.
41. G.
Sepulveda, M. Rosa-Brussin, N. Carrión y A. Morales
"Proceso
para la obtención de ctalizadores en base a arcilla para la hidroconversión y
la HDM de residuos y crudos pesados". Actas del X Simposio Iberoamericano
de Catálisis, vol. II, pág. 1255, 1986 (Mérida/Venezuela).
42. R. B. Solari y A. Morales
"Hidrotratamiento
de aciertes desasfaltados y residuales con alto contenido de metales y
carbón conradson". Actas del II Congreso Colombiano de Petróleo y II Congreso Andino de Petróleo,
Tomo II, III-37/72, 1986.
43. A. Morales, A. Salazar, A. Mata,
M. Rosa-Brussin y G. Sepulveda
"Catalizador de arci lla natural para la
desmetalización y la hidroconversión de crudos pesados y residuales". Actas
del II Congreso Colombiano de Petróleo y II Congreso Andino de Petróleo,
Tomo II, III-01/35, 1986.
44. G. Sepulveda, A. Morales y M. Rosa-Brussin
"Efecto
del contenido de hierro en catalizadores de arcilla sobre la desmetalización de crudos pesados". Rev.
Soc. Venezolana de Catálisis, vol. 1, H3-1-1987.
45. A. Morales, A. de Salazar y N.P. Martínez
"Catalysts Development
for residual treatment. Proc. of 12th
World Petroleum Congress, Houston,
PD-22, Group VIII, poster section, mayo,
1987.
46. A. Salazar, E. Rodríguez, .C. González, A. Morales, M-M- de Agudelo y R.
Galiasso
"Catalysts for
hidrotreatement of cracked feedstocks.
Proc. of 2nd South American Ketjen
Catalysts Seminar (H.J. Lovink Ed.), vol. I:2-10, 1987.
47. A.. Morales, C. Ovalles y F. Rosa
"Tendencias
Internacionales de la Química del
Metanol". Rev. Soc. Venezolana de
Química, 10(3): 3-6, jul-sept, 1987.
48. A. Morales, A. Salazar, A. Mata, G.
Sepulveda, M.R. Brussin
"Proceso
en lecho fijo para la desmetalización y la hidroconversión de crudos
pesados y residuales mediante catalizador de arcilla natural. Rev. Técnica INTEVEP, 7(2): 103-116.
julio 1987.
49.A.
Morales, J. A. Salazar Guillen y E.
Rodríguez
"
Hidrocraqueo suave de gasóleos de vacío pesados para la producción de
destilados medios. Rev. Técnica INTEVEP, 7(2):143-148, julio 1987.
50. J. A. Salazar, J. González, E. Rodríguez,
A. Morales y R. Galiasso
"Hydrocraqueo
suave (MHC): una ruta económica para
producir mayor cantidad de diesel oil. Rev. Técnica INTEVEP, 7(2):123-133,
julio 1987.
51. A. Morales
Mercado
mundial de catalizadores. Rev. Sociedad
Venezolana de Química, 10(4):13-16, oct-dic, 1987.
52. A. Morales, M.M. de Agudelo, F. Hernández y Ricardo Prada Silvy
"Efectos del fósforo
sobre las propiedades físico-químicas y catalíticas del catalizador
CoMoA12O3. Actas del X Simposio Iberoamericano de Catálisis (F. Cossio, O. Bermúdez,
G. del Angel y R. Gómez Editores), Vol. II, 1059-1065, México 1988.
53. A. Morales y M.M. de Agudelo
"Promoter effect of phosphorus in
NiMoP-A12O3 catalysts on HDN Reaction. Proc.
of 9th International Congress on Catalysis.
(M. J. Phillips and M. Ternan Editors),
vol. I, 42-49, Calgary, Canada, 1988.
54. A. Morales, M.M. de Agudelo y F. Hernández
K.
"Mechanism of
phosphorus adsorption on alumina". Appl. Catal., 41:261-271, 1988.
55. A.
Morales
"Proceso
de Conversión del Gas Natural a líquidos. Presente y Futuro", Rev. Soc. Venezolana
Química, 12, N° 1, enero-marzo 1989.
56. M. Cubeiro, M. Goldwasser, V. Baez, F. Parra y
A. Morales
"Evaluación
a Escala banco de Catalizadores para la hidrogenación de Co"., Actas de X Encuentro Nacional de Catálisis, Soc.
Venezolana de Catálisis, INTEVEP, S.A.
3-5 mayo, 1989.
57. E. Manrique, J. Pérez, M. Goldwasser, J.
García, J. Tejada y A. Morales
Preparación y Caracterización de
Catalizadores de Cobalto, Co-Mo y Ruterio soportados sobre TiO2 para la reacción de hidrogenación de Co. Actas del X Encuentro Nacional de Catalisis, INTEVEP, S.A. ,
3-5 mayo 1989.
58. F. Avendaño. A. Montes, J. Tejada, J.
García y A. Morales
"Transformación
de metano y propano sobre catalizadores superácidos".Actas del 12º
Simposio Iberoamericano de Catálisis, Brasil, Río, vol. II, pág.
930, 1990
59. A. Morales, J. Labinger y S. Li.
"Nuevos
catalizadores soportados sobre b"-Alumina para el acoplamiento oxidativo y
oxidación profunda del metano".
Actas del 13o. Simposio Iberoamericano de Catálisis, España, Sevilla, vol. VI, pág. 59, 1992.
60. A. Morales, R. Prada Silvy y V. León
"New Catalytic Phases
for HDN and MHC Reactions in CoMoP- Alumina Catalyst", Proc. 10th International Congress on
Catalysis. New Frontiers in Catalysis,
Part C, pag. 1899 (L. Guczi, F. Solymosi and P. Tetenyi Eds.) Budapest,
Hungary, julio 1992.
61. A.
Morales, S. Rodríguez y F. Mc Carty
"Inteligencia Tecnológica: Un nuevo proceso para la toma de decisiones
gerenciales", Rev. Visión
Tecnológica, vol. 1(1):64-67, 1993.
62. A.
Morales
"Acoplamiento oxidativo de metano
sobre catalizadores bimetalicos -b"-
Alumina. XIV Simposio
Iberoamericano de Catálisis, Concepción, Chile, (Editor: Soc. Chilena de Química),
vol. 1: pág. 98, 1994.
63.- A.
Morales
"
Efecto sinergético del manganeso y el estrocio en la reacción de acoplamiento
oxidativo del metano usando catalizadores bimetalicos sobre
b"-alúmina". Rev. Soc. Venezolana de Catálisis,
vol.7, 31-43, 1994.
64.- A. Morales, N.P. Martínez y R. Monque,
" Catalyst needs in the refining Industry", Worldwide Catalyst Industry Conference, CATCON´94, junio
26-28, Philadelphia.
65. B. Solari y A. Morales
" Process Schemes for Hydrotreatment of Deasphalted oil and
Residuals", Catalyst in
Petroleum Refining and Petrochemical
Industries 1995, M. Absi et al. (Editors),
Elsevier Science, 125-133, 1996.
66.- A. Morales, J.J. García, J. M.
Garnica, E. F. Rondón, E. Romero, F. Perez Santana
Las celdas de combustible, presente, futuro
y su impacto en la industria petrolera, Rev. Visión Tecnológica, vol.4(1):63-69, 1996.
67.- A. Morales
Tendencias del mercado Mundial de
Catalizadores de Refinación, Boletín de la Sociedad Química del Perú, 232-237,
1996.
Rev. Visión
Tecnológica, vol.3(2):53-58, 1996.
68.- A. Morales, A. Salazar, C. Ovalles y
E. Filgueiras
Hydroconversion of Heavy Crudes Oils using Soluble Metallic Compounds in
the presence of hydrogen or
methane. 11th International Congress on Catalysis, 40th Anniversary, Studies
in Surface Science and Catalysis J.W. Higtower et al. (Eds), vol.101, pág.
1215- 1222, 1996.
69.- A. Morales y B. Solari
Hydrotreatment of Residuals
Using a Special NiMo-Alumina Catalyst. In Catalyst
in Petroleum Refining and Petrochemical Industries 1995. M. Absi-Halabi et
al. (editors). Elsevier Science B. V. 1996.
70.-
F. Avendaño, J. Tejada, J.J. García y A.
Morales
Estudio
de Actividad de Catalizadores Tipo Superácidos
mediante la Transformación de
Metano y Propano. Rev. Soc. Venezolana de
Catálisis, vol.9, 12-17, 1995 (La revista fue publicada en marzo de 1997).
71.- A. Morales
Proceso
Exitoso de Transferencia de Tecnología en el caso de Catalizadores Nacionales. Rev. Visión
Tecnológica, vol.4(2):189-194, 1997.
72.
A. Morales y Otto Rodríguez
Modelo
para la Propiedad, Protección y
Comercialización de Tecnología en Venezuela,
Rev. Visión Tecnológica,
vol.5(1):79-84, 1997.
73.- C. Ovalles, F. Figueiras, A. Morales,
C. E. Scott y F. González-Giménez
Use of a dispersed iron catalyst for upgrading extra-heavy crude
oil using methane as source of hydrogen. Preprints
of 216th ACS National Meeting. Boston, MA.;August 22-27, 1998;
vol. 43(3):521-525.
74.- C. Ovalles, F. Figueiras, A. Morales,
I. Torres. J.C. de Jesús e I. Berrios
Use of a Dispersed
Molybdenum Catalyst and Mechanistic Studies for Upgrading of Extra-heavy Crude
Oil Using Methane as Source of Hydrogen. Energy & Fuel, 12:379-385, 1998.
75.-
P. Andréu, R. Prada Silvy y A: Morales
Análisis
de las tendencias tecnológicas mundiales en refinación y el mercado de
catalizadores XVI Congreso Iberoamericano de Catálisis. Cartágena, Colombia,
1998.
76.- A. Morales, C. Marrero, M. A. Agüero
La gerencia
del conocimiento y el Centro de Información Técnica de PDVSA-Intevep. Rev. Visión Tecnológica, vol. 7(1):47-52,
1999.
THESIS
1. Tesis de licenciado en quÍmica:
"Requerimiento de iones metálicos divalentes, para la
activación de la Lipoproteína Lipasa por el Confector Sérico"
Universidad Central de
Venezuela, diciembre 1972
Jurado: I. Posner, W. Jaffe y G. Cadavic.
2. TRABAJO DE INVESTIGACIÓN PARA EL D.E.A.
"Etude des reactions
catalytiques d'échange de l'éthane et du cyclopentane avec le deuterium, sur
platine deposé sur alumine".
Universidad de Poitiers,
Francia, junio 1975.
Jurado: R. Maurel, M. Guisnet, G. Leclercq y J.
Barbier.
3. TESIS DE DOCTOR DE TERCER CICLO.
"Comparison,
sur platine, de pleusiers réactions
sensible a la estructure du catalyseur".
Universidad de Poitiers,
Francia, junio 1976.
Jurado:
R. Maurel (Presidente), M. Guisnet, C. Marcilly y J. Barbier
(examinadores)
4. TESIS DE DOCTORADO DE ESTADO.
"Influence de la
dispersion du platine et de son empoisonnement
sur son activité et sa selectivité pour diverses reactions tests".
Universidad de Poitiers,
Francia, junio 1978.
Jurado: J.E. Germain (Presidente), R. Maurel, P.C.
Gravelle, G. Martino, A. Cointot y J. Barbier (examinadores).
Exhibition on scientific and technological contributions, their
participation in the training of senior staff and the impact of their work in
society
1 .- Establishment of the mechanism of
surface activation of phosphorus in the CoMo and NiMo catalysts supported on
alumina. These catalytic systems are the basis for producing and refining
petroleum products. The action of phosphorus possible to reduce coke production
and extend the lifespan of those with a consequent saving of foreign exchange
for the oil industry.
2 .- Discovery of the mechanism of
demetallization reactions by heavy crude oils using models ofl extracted
porphyrins from petroleum oil,, which allowed to extrapolate the basic results
for the production of active catalysts for this process.
3 .- Development of technological processes
for improving heavy crude from the Orinoco Belt, enabling worldwide recognition
for the positioning of Venezuela in that area.
4 .- Production of catalysts from laboratory
level to industrial or commercial level. Being first in the country that
reaches such a level for such products of high commercial value and strategic
importance to Venezuela.
5 .- The technological developments of the
applicant in the areas of applied catalysis, processes heavy crude hydrotreatment
and commercial scale catalysts, first allowed to market and license a
Venezuelan technology internationally. Four (4) of his inventions have been
commercialized by PDVSA and purchased by Exxon for its U.S. refineries and
England (Fowles). The license given to Akzo Chemical, Holland for the
manufacture of catalytic systems, allowed PDVSA sales of several million
dollars.
Training
of senior staff ( Thesis of degree )
1. Francisco
Machado
"Obtención
de soportes catalíticos activos". Degree in
Chemistry from the Universidad Central de Venezuela 1975.
2. Manuel
Aguiar
"Mecanismo
de adsorción de porfirinas de Boscan sobre catalizadores de
hidrodesmetalización oxidados". Degree in
Chemistry from the Universidad Central de Venezuela UCV, 1981.
3. Víctor
Añez
"Desarrollo
y selección de catalizadores de hidrodesmetalización". Degree in Chemistry from the Universidad Central de Venezuela, UCV, ,
julio 1981.
4. Carmen
Marrero
"Mecanismo
de adsorción de porfirinas de Boscan sobre catalizadores de
hidrodesmetalización reducidos". Degree in
Chemistry from the Universidad Central de Venezuela, UCV, julio 1981.
5. Nelsón
E. Navarrete Franco
"Síntesis
de catalizadores partiendo de asfaltenos de Boscan. Degree in
Chemistry from the Universidad Central de Venezuela, UCV, , agosto 1981.
6. Ricardo Prada Silvy
"Reactividades de las
petroporfirinas sobre catalizadores Co-Alúmina y Mo-Alúmina". Degree in Chemistry from the Universidad Central de Venezuela, UCV, , Julio
1981. (Trabajo dirigido conjuntamente con el Prof. Orlando Abrams y el Prof.
L. Katan).
7. Flor Hernández Krone
"Efecto del fósforo sobre las
propiedades físico-químicas y
catalíticas del
catalizador CoMoA1203". Degree in Chemistry from the Universidad Central de
Venezuela, UCV, abril 1986.
8. Yasmina Mujica
"Efectos del boro y del fósforo-boro sobre
las propiedades físico-químicas y
catalíticas del catalizador CoMo-A12O3". Degree in Chemistry from
the Universidad Central de Venezuela, UCV, Oct 1987.
The
impact of their work in society:
The technological developments of the
applicant in the areas of applied catalysis, processes of hydrotreatment of
heavy crude and commercial scale catalysts, allowed for first time to market
and license a Venezuelan technology internationally. Four (4) of his inventions
have been commercialized by PDVSA and purchased by Exxon for its U.S.
refineries and England (Fowles). The license given to Akzo Chemical, Holland
for the manufacture of catalytic systems, allowed PDVSA sales of several
million dollars. On the other hand, his
invents to give to PDVSA one
technological position in the world in
this area.
ASSOCIATION
1.- Association for the Advancement of
Science, ASOVAC
2. College of chemists, biologists, physicists
and mathematicians of Venezuelan.
3.
Chemical Sociaty of France, Member from 1978
4.
Venezuelan Sociaty of Catalysis,
Member from 1977.
5.
Licensing Executive Society,
LES, Venezuelan Chapter, founding member.
6.
American Chemical Society,
from 1992, member.
8.- Academy of Sciences of New York, from 1994
ALFREDO LUIS
MORALES RUIZ
CEDULA
DE IDENTIDAD N° 2.921.612
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